carbanide, chloropalladium(1+),(1Z,5Z)-cycloocta-1,5-diene CAS:63936-85-6

Isku-dhafka Palladium(II) Chloro [(C8H12)(Cl)Pd] waxaa lagu sameeyaa isku-dubaridka u dhexeeya PdCl4 iyo molecules-ka trans-(1R,5S)-cycloocta-1,5-diene iyada oo loo marayo isku-xidhka dative. Badeecada ka dhalata waxay ka kooban tahay hal ligand dienyl ah oo ku xiran mid kasta oo ka mid ah afarta xarun ee birta ah iyada oo loo marayo isku-dubaridka eta. Isku-dhafkan wuxuu leeyahay xasillooni kuleyl oo sare sababtoo ah xoogagga isku-dhafka ah ee xooggan ee ku jira qaab-dhismeedka. Codsigiisu wuxuu inta badan ku jiraa hababka kicinta ee ku lug leh fal-celinta isku-xidhka isku-dhafka ah. Tusaale ahaan, noocaan wuxuu fududeeyaa sameynta isku-xidhka C-C inta lagu jiro Fal-celinta Isku-xidhka Suzuki kaas oo ku lug leh isku-darka atomyada kaarboonka ee sp2 iyadoo la adeegsanayo asiidhyada boronic sida nucleophiles. Isku-xidhka cusub ee ka dhashay wuxuu kor u qaadaa sifooyinka walxaha loo isticmaalo aaladaha elektaroonigga ah sidaas darteedna wuxuu ka dhigayaa mid aad u hufan. Intaa waxaa dheer, kicintani waxay ka heshaa codsiga falcelinta isku-xidhka Sonogashira halkaas oo atomyada isku-dhafka ah ee sp lagu xidho iyadoo la isticmaalayo alkynes terminal taasoo horseedaysa sameynta isku-xidhka C-C taasoo samaysa kooxo shaqo oo cusub oo leh codsiyo suurtagal ah oo ku saabsan dhinacyo kala duwan oo ay ku jiraan isku-darka daawada iyo sayniska agabka.